Toshirō Hitsugaya

Confident, Very Calm, Very Ethical Toshirō Hitsugaya is the Captain of Squad 10 of the Gotei 13. Due to him being the youngest Captain,he's the smallest Captain,but is also seen as a Prodigy. He hands spiky white hair,and green eyes. Despite him being mature for someone his age,a few Coptains still treat him like a child,like Jushirō,who hands him snacks and candy

Jushirō Ukitake

Very Brave, Very Free-spirited, Very Loyal, Idealistic Jushirō Ukitake is the Captain of Squad 13,his Lieutenant Rukia Kuchiki. He has long silver hair and hazel eyes.

Byakuya Kuchiki

Very Confident, Arrogant, Idealistic, Very Ethical Byakuya Kuchiki,Captain of Squad 6,has long black hair,dark eyes,and three bangs covering the front of his face,and another one to the side,each one covered by a triangular prism shaped plate a top his head. His Zanpuktō, Senbonzakura,allows him to transform his blade into a thousand tiny pieces that shine like cherry blossoms in its Shikai state,his Bankai allowing him to use more blades that are sharper than before at twice the speed,and his Senkai,a third form of sorts,allowing him to create a sort of dome of blades around him and his enemy,making him a dangerous opponent. He,however,does not like to be social,and is not necessarily good at telling jokes,holding a good conversation,etc

Genryūsai Shigekuni Yamamoto

Very Focused, Very Likeable, Compassionate, Very Confident Genryūsai Shigekuni Yamamoto,otherwise known as Old Man Yama by some of the Captains,is the Head Captain of the Gotei 13. His appearance is that of a old man -Somewhat wrinklely,very long beard,long eyebrows,all grey hair,and no hair atop his head,with a scar on his scalp- but isn't to be underestimated. His Zanpuktō,Ryūjjin Jakka,grants him the power of fire that grows stronger with every Soul he defeats,Hollows included. His Bankai allows him to summon the souls of those he's defeated as his Undead Army. Despite this,outside the battlefield,he is a peaceful man,and can sometimes act as a grandfather of sorts -Especially with Yachiru- and given the fact that he walks with his back hunched and with a cane,further cements that notion. He,like any other elderly person,demands respect,especially when it comes to the Gotei 13's image,the Captain's Haoris being the main example

SoiFon

Very Headstrong, Very Focused, Empathetic SoiFon,despite being one of the shortest Captains,has a rather cold and aggressive behaviour. She has short black hair,dark eyes and wears a sleeveless Haori. Being the current Commander of the Stealth Force,and Captain of Squad 2,she is small but powerful. Although she's not one to take insults lightly,especially about her height,she has a,although hard to find,soft side

Retsu Unohana

Very Headstrong, Very Confident, Very Professional Retsu Unohana,otherwise known as the First Kenpachi,is now Captain of Squad 4. She has long black braided hair,and grey eyes. She maintained her kind and gentle demeanor,up until the Thousand Year Blood War,where her true identity was revealed,Yachiru Unohana -A blood thirsty Serial killer who has masked herself with the facade of a gentle woman- The First Kenpachi