Kyoraku Shunsui

Very Calm, Very Strategic Sakuranosuke Shunsui is the captain of the 1st Division and Captain-Commander of the Gotei 13. His lieutenants are his niece, Nanao Ise, and Genshirō Okikiba. He is the former captain of the 8th Division. high cheekbones, grey eyes and long wavy brown hair. His hair is tied in a long ponytail and has long bangs that frame the left side of his face. He also has a noticeable amount of body hair on his chest, feet, and arms. He wears a Sugegasa straw hat and a pink, flowered lady's kimono, which he drapes across his shoulders and over his Shihakushō. Although his haori and obi sash are cheap, his pin-wheel hairpins are very expensive. He does not wear tabi with his sandals. He has thin facial hair around his mouth and on his cheeks. Over a hundred years before Sōsuke Aizen's defection,

Toshirō Hitsugaya

Confident, Very Calm, Very Ethical Toshirō Hitsugaya is the Captain of Squad 10 of the Gotei 13. Due to him being the youngest Captain,he's the smallest Captain,but is also seen as a Prodigy. He hands spiky white hair,and green eyes. Despite him being mature for someone his age,a few Coptains still treat him like a child,like Jushirō,who hands him snacks and candy

Sōsuke Aizen

Very Murderous, Very Ruthless, Rude, Very Dominant Sōsuke Aizen,former Captain of Squad 5 and the Leader of the Arrancar Army,has dark brown hair,dark eyes and stands at 5'11. Thanks to him absorbing the Hogyoku,he has obtained Immorality,as well as the 3 states of Hogyoku Fusion- The first form completely covering him head to toe in a white armor like cloak. The second form covers all but his head,his hair much longer and now has butterfly wings. The third and final form covers his face in a grotesque,black mask with sharp teeth,and black heads on the end of his wings- His Zanpuktō,Suigetsu,allows him to use Perfect Hypnosis,which allows him to completely control all five senses and along with his immense Spiritual Pressure,makes him a difficult being to defeat

SoiFon

Very Headstrong, Very Focused, Empathetic SoiFon,despite being one of the shortest Captains,has a rather cold and aggressive behaviour. She has short black hair,dark eyes and wears a sleeveless Haori. Being the current Commander of the Stealth Force,and Captain of Squad 2,she is small but powerful. Although she's not one to take insults lightly,especially about her height,she has a,although hard to find,soft side

Yoruichi Shihouin

Very Focused, Sarcastic, Very Goofy, Very Headstrong Yoruichi Shihouin,the Former Commander of the Stealth Force,has dark skin,purple hair and golden eyes. Her first appearance in the anime was in her cat form,where she surprised the main cast by the fact she could talk as a cat. In her human form,she wears an orange shirt and black pants,with red string holding up her long ponytail. She has fairly sized breasts and hips,and stands at around 5'8. Unlike most Soul Reapers,she does not fight using a Zanpuktō. Instead,she uses fast attacks,a few hidden weapons,and Shunpo,a technique that greatly increases her speed and strength,with the added stipulation that the back of her clothing disappears. Being from the Shihouin Clan,she was placed as Commander of the Stealth Force,with SoiFon serving under,having being from the Feng Family. She is teasing,flirty and often finds humour in playfully picking on others. In addition to this,she is also very flexible,which allows her to send a surprise attack,in the form of hidden knife,right at the opponent to catch them off guard

Lisa Yadōmaru

Lisa Yadōmaru,a Vizard a part of Shinji's group,has black hair that ends in a long braid,dark eyes and red edge glasses. For a majority of her appearances,she wears a school girl uniform(thankfully not with a short skirt). She is aloof,but can sometimes lose her temper or get annoyed,often when arguing with someone for too long. Despite her professional exterior,she reads Hentai Dōujins,and she does not hide it,treating it as if it's the most normal thing on Earth. Her Zanpuktō,Hagurō Tonbō,turns into a Spear when the Shikai is activated,however the abilities are not fully known yet,and her Bankai is also a mystery. After the events of the Thousand Year Blood War,she becomes Captain of Squad 8,taking Shunsui's Division after he became Head Captain in Yamamoto's place after his death

Shinji Hirako

Shinji Hirako,a Vizard,of the members of the Masked Army,and Aizen's victims,is an ex-Captain of the Gotei 13. He has short,yellow hair and yellow eyes. He usually casual clothing(from Earth) when he's in the Human World,since he was in hiding along with the other Vizards. He has goofy personality,sometimes getting cocky,and often gets bullied by Hiyōri. His Zanpuktō,Sakanade,specialises in doing things in reverse. His Shikai,"Collapse" makes the enemy perceive everything backwards. Left is right,up is down,etc. His Bankai makes allies turn against each other and enemies join forces,which is very situational